MSDS-IPPD
STAIR CHEMICAL & TECHNOLOGY CO., LTD.SHANDONG
MIDDLE SESSION OF NANHUAN ROAD, CAOXIAN, SHANDONG, CHINA
TEL: 86-530-3205777 FAX: 86-530-3366666 http://www.stairchem.com
Material Safety Data Sheet IPPD
- IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
PRODUCT NAME: STAIR IPPD
MSDS NO.: STAIR 0009
Chemical Name: N-isopropyl-N'-phenyl-p-phenylenediamine Synonyms: 4010NA; N-isopropyl-N'-phenyl-p-phenylenediamine Use: Antidegradant
Manufactured By: Stair Chemical&Technology Co., Ltd Shandong
Address: Middle Session of Nanhuan Road, Caoxian, Shandong Province, China. Tel. + 86 530 3205777
Fax. + 86 530 3366666
Emergency Telephone: +86 530 3205777
- COMPOSITION/INFORMATION ON INGREDIENTS
PRODUCT DESCRIPTION N-isopropyl-N'-phenyl-p-phenylenediamine,
HAZARDOUS INGREDIENT(S) CAS No % (W/W) Symbol R Phrases
N-isopropyl-N'- phenyl- 101-72-4 >97 Xn,N R22/43, p-phenylenediamine R50/53
(Impurities may contain a second isopropyl group (on Nitrogen) or do not contain the isopropyl group)
- HAZARDS IDENTIFICATION
May cause skin sensitisation
Inhalation of high concentrations may cause CNS depression and lung damage May cause eye irritation
May be absorbed through skin See: OTHER INFORMATION
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
- FIRST-AID MEASURES
Inhalation Remove patient from exposure. Obtain medical attention if ill effects occur. Skin Contact Remove contaminated clothing. Wash immediately with soap and water. If symptoms (irritation or blistering) occur obtain medical attention.
Contaminated clothing should be laundered before re-issue.
Eye Contact Irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes. Obtain medical attention. Ingestion Do not induce vomiting. Wash out mouth with water and give 200-300 ml (half a pint) of water to drink. Obtain medical attention.
Further Medical Treatment
Symptomatic treatment and supportive therapy as indicated. See: OTHER INFORMATION
- FIRE-FIGHTING MEASURES
Flash Point: >200°C
Protect from sparks (dust explosion risk)
Mixing with high surface area adsorbents generates heat which can ignite the powder or surrounding materials. If involved in a fire emits toxic fumes.
Thermal decomposition products: Oxides of Carbon and Nitrogen
Extinguishing Media As appropriate for surrounding materials/equipment. Use water spray (with care to avoid possible violent production of steam) to keep the container cool, foam and dry chemical.
Fire Fighting A self contained breathing apparatus and suitable
Protective Equipment : protective clothing should be worn in fire conditions.
- ACCIDENTAL RELEASE MEASURES
Do not allow to enter drains, sewers or watercourses. Use appropriate containment to avoid environmental contamination. Clear up spillages. Transfer to a container for disposal or recovery. Ensure suitable personal
protection during removal of spillages. Spillages or uncontrolled discharges into watercourses must be alerted to the appropriate regulatory body.
- HANDLING AND STORAGE HANDLING
Avoid contact with skin and eyes. Avoid breathing vapours/contact with hot liquid.
STORAGE
Keep away from oxidising agents, acids, alkalis, moisture, heat and direct sunlight. Incompatible with strong oxidising agents
Suitable containers: Corrugated paper box with polythene liner inside. Storage Temperature: Ambient.
Storage Life: 1 year(s)
- EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear suitable gloves and eye/face protection.
Provide natural or mechanical ventilation to minimise exposure.
Occupational Exposure Limits
No occupational exposure limit listed but 2.5 mg/m3 is recommended
- PHYSICAL AND CHEMICAL PROPERTIES
Form Beads
Colour Dark brown, severely staining Odour Aromatic
Odour Threshold (ppm) No data. pH (Value) No data.
Boiling Point (Deg C) 220°C @ 1.33 kPa Melting Point (Deg C) 70 (min)
Flash Point (Deg C) >200 Flammable Limits No data. Auto Ignition Temp (°C) >500
Explosive Properties Not applicable. Oxidising Properties No data.
Solubility (Water) (15 mg/l), Practically insoluble Solubility (Other) Soluble in acetone
Specific Gravity @ 25°C 1.1 (typical) Molecular Weight 226.32
Molecular Formula C15H18N2
- STABILITY AND REACTIVITY
Chemical Stability Stable under NTP
Incompatible materials Oxidising agents (H2O2, Cl2), acids and alkalis. Hazardous Reactions None known.
Conditions to avoid Heat, flame & sparks. Do not store near insoluble sulphur Hazardous Polymerisation will not occur
Hazardous Decomposition: Nitrogen oxides, carbon monoxide, carbon Product(s) dioxide. (See Section 5).
- TOXICOLOGICAL INFORMATION
Oral Acute oral LD50 (Rat): 900 mg/kg
Inhalation Combustion will evolve very toxic and irritant vapours. Skin Contact May cause sensitisation by skin contact.
. Acute Dermal LD50 (Rabbit) : >7500 mg/kg
Eye Contact May cause mild eye irritation. Slight/mild irritant to rabbit eyes. Ingestion Low oral toxicity.
Long Term Exposure A study in animals has shown that repeated doses produce slight foetotoxic effects but no teratogenic effects.
- ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Solid with low volatility.
The substance is sparingly soluble in water.
The substance has potential for bioaccumulation.
Acute Fish Toxicity: 96 hrs LC50 (Bluegill Sunfish): 0.43 mg/l 96 hrs LC50 (Rainbow Trout): 0.34 mg/l
96 hrs LC50 (Flathead Minnows): 0.41 mg/l
Acute Crustaceans 48 hrs LC50 (Daphnia Magna): 1.10 mg/l Acute Algae Toxicity 96 hrs EC50 (Green Algae): 0.40 mg/l
Octanol/Water Partition Coefficient: LogP=3.88 Bioconcentration Factor: 170 (Calculated)
- DISPOSAL CONSIDERATIONS
This material and/or its container must be disposed of as hazardous waste. Disposal should be in accordance with local, state or national legislation.
- TRANSPORT INFORMATION
DOT: Not Regulated
DOT Reportable Quantity (lbs): None
ICAO/IATA: See DOT
IMDG: See DOT
Marine Pollutant: No TDG (Canada): See DOT Remarks: None
- REGULATORY INFORMATION
EC Classification Harmful, Xn Dangerous for the environment, N
Risk Phrases R22 Harmful if swallowed. R43 May cause sensitisation by skin contact R50 Very toxic to aquatic organisms
R53 May cause long-term adverse effects in the aquatic environment. Safety Phrases S24 Avoid contact with skin.
S25 Avoid contact with the eyes.
S36 Wear suitable protective clothing.
S57 Use appropriate containment to avoid environmental contamination.
S60 This material and/or its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheet.
- OTHER INFORMATION
Use : Antioxidant/antiozonant for the rubber industry
Special notes: Tests by Hen/e-Bazin et al demonstrate that IPPD is comparable with 6PPD in its skin sensitisation potential. Cross-sensitisation between IPPD and
other p-phenylene diamine antidegradants has also been observed and reported.
Reference:
Herve-Bazin, B. et al, Occupational eczema from N-isopropyl-N’-phenyl-pphenylenediamine (IPPD) and N-dimethyl-1, 3-butyl-N’-phenyl-p-phenylene diamine
(DMPPD) in tyres. Contact Dermatitis, 1977; 3: 1-15. OECS SIDS on N-isopropyl-N’-phenyl-p-phenylenediamine,
(Reference: SIDS Initial Assessment Report for SIAM 10, Tokyo 15-17, March 2000) HMIS rating: Health: 1
Flammability: 1
Reactivity: 0 PPI: X
Legend: 0(HMIS) Minimal hazard 1(HMIS) Slight hazard
2(HMIS) Moderate hazard 3(HMIS) Serious hazard 4(HMIS) Severe hazard
X (HMIS) Personal protective rating to be supplied by user depending on the use conditions
Information in this publication is believed to be accurate and is given in good faith, but it is for the Customer to satisfy itself of the suitability for its own particular purpose. Accordingly, STAIR gives no warranty as to the fitness of the Product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent of such exclusion is prevented by law.
